Product ID:UNDERCOATS SPRAY, 4500
MSDS Date:09/01/1992
FSC:6850
NIIN:00N045482
MSDS Number: BTXGP

MARTIN-SENOUR CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: MART2

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

SPEC PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

APPARENT. OBTAIN MEDICAL ATTENTION.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ALL FLAMES, PILOT LIGHTS,& HEATERS-TURN

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

OF IGNIT. CONSULT NFPA CODE.USE APPRVD BONDING &

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

INCIN/EXPOS TO TEMPS ABOVE 120F, HEAT FROM

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

COULD CAUSE CONTAINER TO BURST. DO NOT TAKE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

MAY CONTAIN MATLS CLASSIFIED AS NUISANCE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

PRESENT AT HAZ LEVS ONLY DURING SANDING/ABRADING OF

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

APPLIC LIMITS FOR NUISANCE DUSTS ARE ACGIH TLV 10

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

760.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 15%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760.

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: 5%

OSHA PEL N/K

ACGIH TLV: N/K

127.

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 30%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

12.

CAS: 64742-89-8

Fraction By Weight: 3%

OSHA PEL 300 PPM;400 STEL

ACGIH TLV: 300 PPM

22.

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 5%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9.

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 7%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ASPHALT (PETROLEUM)

CAS: 8052-42-4

RTECS: CI9900000

Fraction By Weight: 10%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

ALUMINOSILICATE

CAS: 1327-36-2

Fraction By Weight: 3%

OSHA PEL 10 MG/M3;5 RDUST

ACGIH TLV: 10 MG/M3

TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)

CAS: 14807-96-6

RTECS: WW2710000

Fraction By Weight: 4%

OSHA PEL 2 MG/M3 RDUST

ACGIH TLV: 2 MG/M3 RDUST

CALCIUM CARBONATE

CAS: 471-34-1

RTECS: EV9580000

Fraction By Weight: 3%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 3%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

NEUROPATHY), RSLTG IN MUSCULAR WEAK & LOSS OF

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ETHYL KETONE. PRLNGD OVEREXP TO SOLV INGS IN ING

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

FORMING, CARDIOVASCULAR, & REPROD SYS.RPTS HAVE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

TOLUENE,108-88-3, APPEARS ON NAVY

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

APPROP HEALTH PROFESSIONALS CONCERNING LATEST HAZ

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. CHRONIC: SOME ANIMAL STUDIES W/POOR CNTRLS INDICATED
THAT BITUMENS (ASPHALT) CAUSE TUM ORS. HOWEVER, THERE IS INADEQ
EVIDENCE THAT BITUMENS ALONE ARE CARCIN TO HUMANS. PRLNGD & RPTD
OVEREXP TO HEXANE(SUPDAT)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF
COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR
SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE
EYE OR EXCESSIVE SKIN EXPOSU RE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND
WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
EYES: FLUSH W ITH LARGE AMOUNTS OF WATER FOR AT LEAST15 MINUTES.
GET MEDICAL ATTENTION. INGESTION: SEEK MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.5%
Upper Limits:12.9%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP.WATER SPRAY MAY BE INEFT.IF WATER USED,FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS,& OPEN FLAME. CLSD CNTNRS MAY EXPLO WHEN
EXPOS TO EXTREME HEAT. APPLIC TO HOT SURFS REQS(ING 17)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS ARE EXTREM FLAMM. KEEP AWAY
FROM HEAT, SPARKS, & OPEN FLAME. DURING USE & UNTIL ALL VAPS ARE
GONE: KEEP AREA VENT-DO NOT SMOKE-EXTING(ING 19)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN
BE HARMFUL/FATAL. EXPOS MAY BE BY INHAL &/OR SKIN OR EYE CONT,
DEPENDING ON CONDITIONS OF USE. TO MINIMIZE EXPOSURE, FOLLOW RECOM
FOR PROPER USE, VENT, & PERS PROT EQUIP.COATING (ING 23)

Respiratory Protection:IF PERS EXPOS CANNOT BE CNTRLD BELOW APPLIC
LIMITS BY VENT, WEAR NIOSH/MSHA APPRVD PROPERLY FITTED ORG
VAP/PARTICULATE RESP FOR PROT AGAINST MATLS IN ING SEC. WHEN
SANDING/ABRADING DRIED FILM, WEAR NI OSH/MSHA APPRVD RESP FOR DUST
(SUPDAT)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN
ING SEC IS MAINTAINED BELOW APPLIC EXPOS LIMITS.REFER (SUPDAT)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPVD CHEM WORK GOGG W/(OTR PROT EQ
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. EYE PROT:
FULL LGTH FCSHLD .
Work Hygienic Practices:AVOID BREATHING VAPOR AND SPRAY MIST. AVOID
CONTACT WITH SKIN AND EYES. WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS
TO EXTREME HEAT. RESP PROT: WHICH MAY BE GENERATED FROM PROD,
UNDERLYING PAINT/ABRASIVE. VENT: TO OSHA STDS 1910.94, 1910.107,
191 0.108. HLTH HAZ:MAY CAUSE DMG TO NERV TISS OF ARMS & LEGS
(PERIPHERAL (ING 12)

HCC:V3
Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>70

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, HYDROGEN CHLORIDE.

Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZ AS DEFINED
UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERM APPLICABLE EPA HAZARDOUS WASTE NUMBERS. DO NOT INCIN.
DEPRESSURIZE CNTNR. DISP OF I /A/W FED, ST, & LOCAL REGS REGARDING
POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.